Remote regio- and stereocontrol by the sulfinyl group: Diels–Alder reaction of sulfinyl dienols and 8,8-dimethylnaphthalene-1,4,5(8H)-trione
نویسندگان
چکیده
a Facultad de Química y Biología, Departamento de Ciencias del Ambiente, Universidad de Santiago de Chile, Avenida B. O’Higgins 3363, Estación Central, Santiago, CP 9160000, Chile Departamento de Ciencias Químicas, Universidad Andrés Bello, Avenida Concepción, Talcahuano 7100, Concepción, Chile Departamento de Ciencias Químicas, Universidad Andrés Bello, República 237, Santiago, Chile Departamento de Química Inorgánica y Analítica, Universidad de Chile, Casilla 233, Santiago 1, Chile Departamento de Química Orgánica y Físico-Química, Universidad de Chile, Casilla 233, Santiago 1, Chile Departamento de Química Orgánica (C-1), Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain
منابع مشابه
Lewis acid-catalyzed asymmetric diels-alder reactions using chiral sulfoxide ligands: chiral 2-(arylsulfinylmethyl)-1,3-oxazoline derivatives.
New chiral sulfoxide-1,3-oxazoline ligands have been developed as chiral ligands for Lewis acid-catalyzed asymmetric Diels-Alder reactions. The use of chiral sulfinyl 1,3-oxazoline ligands in copper(II)-catalyzed asymmetric Diels-Alder reactions provided an endo cycloadduct as a major product with moderate enantioselectivity. A rationale is proposed for the mechanism of the asymmetric induction.
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